Molecular nanoarchitectonics: unification of nanotechnology and molecular/materials science

• Katsuhiko Ariga

Beilstein J. Nanotechnol. 2023, 14, 434–453, doi:10.3762/bjnano.14.35

• are introduced, and future prospects of nanoarchitectonics are discussed. The fusion of basic science and the application of practical functional materials will complete materials chemistry for everything. Keywords: local probe chemistry; materials chemistry; nanoarchitectonics; nanotechnology; on

• molecular structures. Kawai et al. reported that local probe chemistry on an ultrathin NaCl film formed on a Cu(111) surface at 4.3 K led to the conversion of 6,13-dibromopentaleno[1,2-b:4,5-b′]dinaphthalene to a single Sondheimer–Wong diyne (Figure 3) [114]. The structures of the precursor, two

• . Unlike conventional solution synthesis, low-temperature local probe chemistry allows for a free control of the radical state. This kind of local probe chemistry as a synthesis technique opens up the possibility of nanoarchitectonics synthesis of carbon nanomaterials. The tip-induced addition of single